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Affiliation |
Engineering educational research section Applied Chemistry Program |
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Associate Professor |
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Related SDGs |
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MATSUNE Hideki
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Research Areas 【 display / non-display 】
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Manufacturing Technology (Mechanical Engineering, Electrical and Electronic Engineering, Chemical Engineering) / Chemical reaction and process system engineering
Papers 【 display / non-display 】
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Hardi J., Tijsseling T., Takase H., Yoshida M., Shiomori K., Matsune H.
Royal Society Open Science 12 ( 8 ) 2025.8
Publishing type：Research paper (scientific journal) Publisher：Royal Society Open Science
A chitosan (CH) cryogel is a supermacropore material that can be used as an adsorbent. However, its utilization as a metal adsorbent is limited due to its low stability in acidic conditions. A CH cryogel has been modified using tripolyphosphate (TPP) and tannic acid (TA) as biocompatible cross-linkers. TPP increases the stability of the cryogels in acidic solutions, and TA increases their mechanical properties. CH-TPP, CH-TPP2.5-TA, CH-TPP5-TA and CH-TPP7.5-TA cryogels were applied for the adsorption of Cu<sup>2+</sup> ions. The CH-TPP-TA cryogels reached optimum conditions at pH 5.0 with a removal efficiency of 91–96%. The adsorption of Cu<sup>2+</sup> ions by CH-TPP-TA cryogels fits the nonlinear Freundlich isotherm, or Cu<sup>2+</sup> is adsorbed on the heterogeneous cryogels’ surfaces. CH-TPP5-TA has an adsorption capacity up to 109 mg g<sup>−1</sup> at an initial Cu<sup>2+</sup> concentration of 500 mg l<sup>−1</sup>. The adsorption kinetics of Cu<sup>2+</sup> ions follows pseudo-second order. It is interpreted that the adsorption mechanism is generally through chemical interactions. Copper elements are proven to be adsorbed by the cryogel, which is detected by energy-dispersive X-ray analysis. The photographic results show that Cu<sup>2+</sup> ions can be adsorbed into the inner layer of the cryogel. Finally, the CH-TPP-TA cryogel is promising to be used as a biocompatible adsorbent for copper.
DOI： 10.1098/rsos.242274
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Synthesis and Characterization of Chitosan Cryogels Modified by Tripolyphosphate and Tannic Acid Reviewed International coauthorship
Hardi, J., Kiyoyama, S., Matsune, H., & Shiomori, K.
Journal of Chemical Engineering of Japan 57 ( 1 ) 2024.8
Language：English Publishing type：Research paper (scientific journal)
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Takase H., Goya N., Kiyoyama S., Shiomori K., Matsune H.
Gels 10 ( 1 ) 2024.1
Publishing type：Research paper (scientific journal) Publisher：Gels
Hydrophobic cryogels with monolithic supermacropores based on poly-trimethylolpropane trimethacrylate (pTrim) containing 1-(2-Hydroxyl-5-nonyphenyl)ethanone oxime (LIX84-I) were successfully prepared by a cryo-polymerization technique using organic solvents with freezing points between room temperature and around 0 °C as solvents. The prepared cryogels were characterized in terms of macroscopic shape and porous structure. The cryogels had a monolithic supermacroporous structure and high contents of LIX84-I depending on the added amount of the extractant to the monomer solution. The amount of LIX84-I impregnated in the cryogel had a linear relationship with the added amount of LIX84-I in the monomer solution for cryo-polymerization. Cu(II) in the aqueous solution was immediately adsorbed into the cryogel containing LIX84-I.
DOI： 10.3390/gels10010009
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Synthesis of Silver Nanowires using N,N-Dimethylalkylamine Reviewed
Matsune H., Ueno Y., Wakamatsu T., Fujimoto M.A., Shiomori K., Yamamoto T., Kishida M.
Kagaku Kogaku Ronbunshu 50 ( 1 ) 27 - 34 2024
Publishing type：Research paper (scientific journal) Publisher：Kagaku Kogaku Ronbunshu
We report a novel method for the synthesis of silver nanowires (AgNWs). In this method, silver chloride (AgCl) and N,N-dimethyl-dodecylamine hydrochloride (C12H25NMe2·HCl) are used as a silver source and a protecting agent, respectively. Heating of both reagents in N,N-dimethyldodecylamine forms silver chlorocomplex, AgCl1‒nn solving homogeneously in the melting C12H25NMe2·HCl. The addition of the reducing agent, N,N-dibenzylhydroxyamine to the reaction mixture in order to reduce AgCl1‒nn to silver atom (Ag0) gives firstly multiplied twinned nanoparticles (MTPs), and then uniform silver nanowires (AgNWs) with the dimension of 50‒100 nm in thickness and >20 µm in length. Thermogravimetric analysis of the product reveals that highly pure AgNWs containing less organic residues are obtained. We investigate the effects of loading ratios of tertiary amine hydrochlorides to AgCl, the molecular structures of amines, and reaction temperature on the morphologies and yields of the generated AgNWs. We demonstrate that the MTPs are efficiently generated by the reduction reaction of AgCl1‒nn in the presence of tertiary amine hydrochlorides, and that tertiary amine hydrochlorides also play an important role in anisotropic crystal growth of Ag0 to AgNWs through the formation of the MTPs.
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Shiomori K., Matsune H., Inda N.I., Kiyoyama S., Takei T., Yoshida M.
AIP Conference Proceedings 2719 2023.5
Publishing type：Research paper (scientific journal) Publisher：AIP Conference Proceedings
Crosslinked-gel microcapsules immobilized small droplets of phenolic oxime extractant, 1-(2-hydroxy-5-nonylphenyl) ethanone oxime (LIX84-I) were prepared from O/W emulsion using falling-drop method followed by crosslinking of sodium alginate (Na-Alg) by Ca2+ ion and crosslinking of polyvinyl alcohol (PVA) by glutaraldehyde. A lot of fine droplets of LIX84-I were successfully immobilized in the microcapsules. The LIX84-I contents in the microcapsules increased with an increase in the LIX84-I amounts to the aqueous phase. The maximum extracted amounts of Cu(II) increased linearly with the LIX84-I contents with a slope of 1/2 which means two molecules of LIX84-I react with one Cu(II) ion. The extraction rate was not significantly affected by the size of the extractant droplets dispersed in the microcapsules. The microcapsules could be used repeatedly for the extraction and back-extraction of Cu(II).
DOI： 10.1063/5.0133362
MISC 【 display / non-display 】
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Synthesis of carbon nanotube-supported Pt nanoparticles covered with silica layers
Takenaka S., Arike T., Nakagawa K., Matsune H., Kishida M., Tanabe E.
Carbon 46 ( 2 ) 365 - 368 2008.2
Language：Japanese Publishing type：Article, review, commentary, editorial, etc. (bulletin of university, research institution) Publisher：Carbon
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Layered Nanocomposite of close-Packed Gold Nanoparticles and TiO2 Gel Layers
MATSUNE Hideki
Chemistry of Materials 11 ( 1 ) 33 - 35 1999
Language：Japanese Publishing type：Article, review, commentary, editorial, etc. (bulletin of university, research institution)
DOI： 10.1021/cm980687a
Presentations 【 display / non-display 】
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シリカナノカプセルへの薬剤の新規封入方法の開発
池水 廉，松根 英樹，塩盛 弘一郎
化学工学会第54回秋季大会 2023.9.13
Event date： 2023.9.11 - 2023.9.13
Language：Japanese Presentation type：Oral presentation (general)
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芯物質に吸水性塩粉末を用いた液中乾燥法による中空マイクロカプセルの調製と金属抽出剤の含浸内包
小倉楓麻, 松根英樹, 清山史朗, 武井孝行, 吉田昌弘, 塩盛弘一郎
第60回化学関連支部合同九州大会 2023.7.1
Event date： 2023.7.1
Presentation type：Oral presentation (general)
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低分子からなるマトリックスを用いたシリカ中空粒子中への酵素固定化法
田原 舞友花，松根 英樹 ，塩盛 弘一郎
化学関連支部合同九州大会 2022.7.2
Event date： 2022.7.2
Language：Japanese Presentation type：Poster presentation
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逆ライデンフロスト効果を活用したsponge-likeクライオゲル粒子の開発
高瀬 隼・ 塩盛 弘一郎・岡本 行広・ 渡邊 望美・ 松根 英樹・ 馬越 大
化学工学会87年会 2022.3.18
Event date： 2022.3.16 - 2022.3.18
Presentation type：Poster presentation
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ゲルマイクロカプセルへの水溶性成分の高内包化と放出制御
溜水 大和，松根英樹，清山 史郎，武井 孝行， 吉田 昌弘，塩盛 弘一郎
第23回化学工学会学生発表会 2021.3.6 化学工学会
Event date： 2021.3.6
Language：Japanese Presentation type：Oral presentation (general)
Awards 【 display / non-display 】
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化学工学論文集優秀論文賞
2025.3 化学工学会 N,N-ジメチルアルキルアミンを用いた銀ナノワイヤの新規調製法
松根英樹，上野佑貴，若松寿紀，藤本優陽，塩盛弘一郎，山本剛，岸田昌浩
Award type：Honored in official journal of a scientific society, scientific journal
Grant-in-Aid for Scientific Research 【 display / non-display 】
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オリゴシルセスキオキサンを用いた次世代型遺伝子導入剤の開発
Grant number：22K04818 2022.04 - 2026.03
日本学術振興会 科学研究費基金 基盤研究(C)
松根 英樹
Authorship：Principal investigator
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糖ナノ粒子を犠牲母材に用いた酵素内包シリカナノカプセルの新規調製法と機能評価
Grant number：19K05141 2019.04 - 2021.03
日本学術振興会 科学研究費補助金 基盤研究(C)
松根 英樹
Authorship：Principal investigator
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Bio-Inspired化学工学の新展開を志向する「膜場」活用戦略の創成 International coauthorship
Grant number：21H04628 2024.04 - 2026.03
日本学術振興会 科学研究費補助金 基盤研究A
馬越 大
Authorship：Coinvestigator(s)
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微生物のヒ素メチル基転移酵素を内包した高メチル化活性カプセルの開発
Grant number：21K12296 2021.04 - 2024.03
日本学術振興会 科学研究費補助金 基盤研究(C)
宮武 宗利
Authorship：Coinvestigator(s)
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高分子超多孔体に固定化した機能性自己組織分子相の特性解析と分離への応用 International coauthorship
Grant number：20K05198 2020.04 - 2023.03
独立行政法人日本学術振興会 科学研究費補助金 基盤研究(C)
塩盛弘一郎
Authorship：Coinvestigator(s)