Papers - OHE Kaoru
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Adsorption of sulfur-containing amino acid and vitamin on silver (I) immobilized chelating resin Reviewed
T. Oshima, Y. Yamanaka, K. Ohe, Y. Baba
Solv. Extr. Res Develop.Jpn. 16 67 - 77 2009.4
Language:English Publishing type:Research paper (scientific journal)
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Degradation of methyl orange using short-wavelength UV irradiation with oxygen microbubbles
Tasaki T., Wada T., Fujimoto K., Kai S., Ohe K., Oshima T., Baba Y., Kukizaki M.
Journal of Hazardous Materials 162 ( 2-3 ) 1103 - 1110 2009.3
Language:Japanese Publishing type:Research paper (scientific journal) Publisher:Journal of Hazardous Materials
A novel wastewater treatment technique using 8 W low-pressure mercury lamps in the presence of uniform-sized microbubbles (diameter = 5.79 μm) was investigated for the decomposition of methyl orange as a model compound in aqueous solution. Photodegradation experiments were conducted with a BLB black light blue lamp (365 nm), a UV-C germicidal lamp (254 nm) and an ozone lamp (185 nm + 254 nm) both with and without oxygen microbubbles. The results show that the oxygen microbubbles accelerated the decolorization rate of methyl orange under 185 + 254 nm irradiation. In contrast, the microbubbles under 365 and 254 nm irradiation were unaffected on the decolorization of methyl orange. It was found that the pseudo-zero order decolorization reaction constant in microbubble system is 2.1 times higher than that in conventional large bubble system. Total organic carbon (TOC) reduction rate of methyl orange was greatly enhanced by oxygen microbubble under 185 + 254 nm irradiation, however, TOC reduction rate by nitrogen microbubble was much slower than that with 185 + 254 nm irradiation only. Possible reaction mechanisms for the decolorization and mineralization of methyl orange both with oxygen and nitrogen mirobubbles were proposed in this study. © 2008 Elsevier B.V. All rights reserved.
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Adsorption of histidine-containing dipeptides on copper (II) immobilized chelating resin from saline solution Reviewed
T. Oshima, K. Kanemaru, H. Tachiyama, K. Ohe, Y. Baba
J. Chromatogr. B 876 116 - 222 2009.3
Language:English Publishing type:Research paper (scientific journal)
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Adsorption of Amino Acid Derivatives on Calixarene Carboxylic Acid Reviewed
T. Oshima, R.Saisho, K. Ohe, Y. Baba, K. Ohto
Reactive and Functional Polymers 69 105 - 110 2009.2
Language:English Publishing type:Research paper (scientific journal)
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Degradation of methyl orange using short-wavelength UV irradiation with oxygen microbubbles Reviewed
T. Tasaki,T. Wada,K. Fujimoto,S. Kai,K. Ohe ,T. Oshima,Y. Baba,M. Kukizaki
Journal of Hazardous Materials 162 ( 2-3 ) 1103 - 1110 2009.2
Language:English Publishing type:Research paper (scientific journal)
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Adsorption of amino acid derivatives on calixarene carboxylic acid impregnated resins
Oshima T., Saisho R., Ohe K., Baba Y., Ohto K.
Reactive and Functional Polymers 69 ( 2 ) 105 - 110 2009.2
Language:Japanese Publishing type:Research paper (scientific journal) Publisher:Reactive and Functional Polymers
Macrocyclic host molecules calixarene carboxylic acid derivatives are found to act as powerful extractants for biologically important amino compounds. A series of adsorbents were prepared from a methacrylate-based polymer Amberlite XAD-7 by impregnation with various calixarene derivatives, for adsorptive recovery of amino acid derivatives. The larger macrocycles calix[6]arene and calix[8] arene carboxylic acid derivatives were more effective for adsorption of amino acid derivatives on the impregnated resin than the calix[4]arene derivative. Since adsorption proceeds mainly via electrostatic interaction, the carboxylic acid groups introduced into the calixarene platform were important for adsorption of cationic amino acid derivatives. The adsorption selectivity for amino compounds using adsorbent impregnated with the calix[6] arene carboxylic acid derivative depends simply on the hydrophobicity of the adsorbates. © 2008 Elsevier Ltd. All rights reserved.
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OSHIMA Tatsuya, KANEMARU Kenzo, TACHIYAMA Hodzumi, OHE Kaoru, BABA Yoshinari
Journal of chromatography. B, Analytical technologies in the biomedical and life sciences 876 ( 1 ) 116 - 122 2008.12
Language:Japanese Publishing type:Research paper (scientific journal)
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Oshima T., Kanemaru K., Tachiyama H., Ohe K., Baba Y.
Journal of Chromatography B: Analytical Technologies in the Biomedical and Life Sciences 876 ( 1 ) 116 - 122 2008.12
Language:Japanese Publishing type:Research paper (scientific journal) Publisher:Journal of Chromatography B: Analytical Technologies in the Biomedical and Life Sciences
Adsorption of histidine-containing dipeptides such as carnosine (Car) was investigated using copper(II) immobilized cation exchange resins. Adsorption of Car was enhanced using Cu(II) immobilized resins, on the basis of metal affinity interactions. In particular, iminodiacetic acid chelating resin with immobilized Cu(II) (Cu-IDA) can adsorb Car from saline water. Car was adsorbed on Cu-IDA even in the presence of 1000 mM of NaCl. Adsorption of various amino acids on Cu-IDA was compared under same conditions. Histidine and the histidine-containing dipeptides were selectively adsorbed on Cu-IDA over other amino acids, both in the absence and in the presence of NaCl. Therefore, immobilized metal affinity adsorption is an efficient method for recovering histidine-containing dipeptides from saline water. © 2008 Elsevier B.V. All rights reserved.
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Adsorption behaviors of arsenate and arsenite using TiO2-Fe3O4
Kaoru Ohe, Kenji Masukagami, Tatsuya Oshima, Yoshinari Baba
2008 Taiwan /Korea /Japan Chemical Engineering Conference and the 55th Taiwan Institute of Chemical Engineers Annual Conference 2008.11
Language:English Publishing type:Research paper (international conference proceedings)
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Denaturation of Lysozyme Using a Porphyrin Derivative Bearing Multiple Anionic Groups Reviewed
T. Oshima, H. Muto, K. Ohe, Y. Baba
Proceedings of the 12th Asian Pacific Confederation of Chemical Engineering Congres 4-036 2008.9
Language:English Publishing type:Research paper (scientific journal)
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Effect of Oxyanions on Adsorption of As(III) and As(V) Using Magnetite
K.Ohe, Y.Tagai, T.Oshima, Y.Baba
Proceedings of The 5th Japnan/Korea Internationa Symposium on Materials Science and Resources Recycling 138 - 139 2007.12
Language:English Publishing type:Research paper (international conference proceedings)
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Preparation of N-Ligands Grafts Chitosdan Derivateives for Recovery of Precious Metal Ions from Aqueous Solutions
R.P.Dhakal, K.Ohe, T.Oshima, Y.Baba
The Proceedings of The 5th Japan/Korea International Symposium on Materials Science and Resources Recycling 111 - 112 2007.12
Language:English Publishing type:Research paper (international conference proceedings)
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Adsorption Behaviors of Bioactive Amines and Proteins on Phosphorylated Bacterial Cellulose Reviewed
T.Oshima, S.Taguchi, H.Fujiwara, K.Ohe, Y.Baba
Journal of Ion Exchange 18 60 - 63 2007.10
Language:English Publishing type:Research paper (scientific journal)
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Preparation of Palladium-Imprinted Chitosan Derivative and its Adsorption Properties of Precious Metals Reviewed
Y.Baba, K.Ohe, T.Oshima, R.P.Dhakal
Journal of Ion Exchange 18 82 - 87 2007.10
Language:English Publishing type:Research paper (scientific journal)
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Adsorption Behavior of Arsenic Using Spherical Porous Silica Particles Covered with Magnetite Reviewed
K.Ohe, Y.Tagai, T.Oshima, Y.Baba, M.Shimizu, Y.Miyake and T.Horikawa
Journal of Ion Exchange 18 154 - 157 2007.10
Language:English Publishing type:Research paper (scientific journal)
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Removal of As(III) and As(V) in Groundwater Using Ferrite Adsorbents Reviewed
K.Ohe, R.Tomimatsu, T.Oshima, Y.Baba
J. Ion Exchange, 18, 404-407(2007) 18 ( 4 ) 404 - 407 2007.10
Language:English Publishing type:Research paper (scientific journal)
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Adsorption Behavior of Carnosine and Anserine on Copper (II) immobilized cation exchange resins Reviewed
T.Oshima, K.Kanemaru, K.Ohe, Y.Baba
Journal of Ion Exchange 18 46 - 49 2007.10
Language:English Publishing type:Research paper (scientific journal)
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Removal of As(III) and As(V) in Groundwater Using Ferrite Adsorbents
Ohe Kaoru, Tomimatsu Rui, Oshima Tatsuya, Baba Yoshinari
日本イオン交換学会誌 18 ( 4 ) 550 - 553 2007
Language:Japanese Publishing type:Research paper (scientific journal) Publisher:Japan Society of Ion Exchange
Ferrite adsorbents containing magnesium, cobalt, nickel, zinc were prepared in order to remove As (III) and As (V) . They are adsorbents with large specific surface area. The ferrite adsorbents could effectively adsorb As (III) and As (V) at neutral pH. The adsorption percentage of As (III) and As (V) onto cobalt ferrite was larger than the other ferrite adsorbents. The adsorption capacity of cobalt ferrite for As (III) and As (V) was 0.83 and 0.52 mmol/g, respectively. The adsorption capacities of As (III) and As (V) on magnesium ferrites increased with increasing their specific surface area, suggesting that functional groups on the surface participate in the adsorption.
DOI: 10.5182/jaie.18.550
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Baba Yoshinari, Ohe Kaoru, Ohshima Tatsuya, Dhakal Rabindra P.
日本イオン交換学会誌 18 ( 4 ) 226 - 231 2007
Language:Japanese Publishing type:Research paper (scientific journal) Publisher:Japan Society of Ion Exchange
In order to develop highly selective adsorbents for recovery of palladium (II), the palladium (II) -imprinted chitosan derivative (PIPMC) was synthesized using <I>N</I>- [pyridylmethyl] -chitosan (PMC) . The adsorption rate and adsorption equilibrium of precious metals on PIPMC were compared with those on PMC to elucidate the template effects. The adsorption rate of palladium (II) on PIPMC is very fast and equilibrated within one hour, while at least 10 hours is necessary to reach equilibrium by PMC. PIPMC provided the selective chelate formation spaces toward not only templated palladium (II), but gold (III), nickel (II) and copper (II) that commonly form planar complexes. The template effect of palladium (II) was studied by examining the adsorption selectivity and kinetics of palladium (II) using hydrochloric acid and 1 M aqueous ammonium nitrate solution.
DOI: 10.5182/jaie.18.226
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Adsorption Behavior of Arsenic Using Spherical Porous Silica Particles Covered with Magnetite
Ohe Kaoru, Oshima Tatsuya, Baba Yoshinari, Tagai Yasuyuki, Shimizu Masayuki, Miyake Toshikazu, Horikawa Toshihide
日本イオン交換学会誌 18 ( 4 ) 298 - 301 2007
Language:Japanese Publishing type:Research paper (scientific journal) Publisher:Japan Society of Ion Exchange
The adsorption behavior of arsenic from water on spherical porous silica particles (SiMAG) covered with magnetite was investigated under batch equilibrium conditions at 303K. The specific surface area and the pH at zero point of charge of SiMAG were 540 m<SUP>2</SUP>/g and 4.6, respectively. Both of As (V) and As (III) were adsorbed on SiMAG The adsorption of As (V) increased with decreasing pH, while that of As (III) was slightly dependent on pH. The adsorption capacity of SiMAG towards As (V) was 0.85 mmol/g.
DOI: 10.5182/jaie.18.298