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Affiliation |
Engineering educational research section Applied Chemistry Program |
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Title |
Associate Professor |
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Related SDGs |
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MATSUNAGA Naoki
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Degree 【 display / non-display 】
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Doctor (Engineering) ( 2003.3 Kyushu University )
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修士（工学） ( 2000.3 長崎大学 )
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学士（工学） ( 1998.3 長崎大学 )
Research Interests 【 display / non-display 】
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Inorganic materials chemistry
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Functional inorganic material
Research Areas 【 display / non-display 】
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Nanotechnology/Materials / Inorganic materials and properties
Education 【 display / non-display 】
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Kyushu University Interdisciplinary Graduate School of Engineering Sciences Molecular and Material Sciences
- 2003.3
Country：Japan
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Nagasaki University Graduate School, Division of Engineering
- 2000.3
Country：Japan
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Nagasaki University Faculty of Engineering Department of Materials Science and Engineering
- 1998.3
Country：Japan
Campus Career 【 display / non-display 】
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University of Miyazaki Engineering educational research section Applied Chemistry Program Associate Professor
2025.04 - Now
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University of Miyazaki Engineering educational research section Department of Engineering Department of Applied Chemistry Program Associate Professor
2021.04 - 2025.03
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University of Miyazaki Interdisciplinary Graduate school of Agriculture and Engineering Materials and Informatics Associate Professor
2013.04 - Now
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University of Miyazaki Engineering educational research section Department of Environmental Robotics Associate Professor
2012.06 - 2021.03
External Career 【 display / non-display 】
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Kagoshima University Assistant Professor
2007.4 - 2012.5
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Kagoshima University Research Assistant
2005.11 - 2007.3
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財団法人北九州産業学術推進機構 研究員
2003.4 - 2005.10
Professional Memberships 【 display / non-display 】
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化学工学会
2008.4
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日本セラミックス協会
2005.11
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電気化学会
2001.2
Papers 【 display / non-display 】
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Preparation of amorphous precursor for realizing low-temperature NiFe2O4 formation Reviewed
Matsunaga N., Kikuchi K., Tokunaga K., Kohno D., Sakai G.
Bulletin of Materials Science 46 ( 3 ) 2023.9
Authorship：Lead author, Corresponding author Language：English Publishing type：Research paper (scientific journal) Publisher：Bulletin of Materials Science
The present study was conducted to prepare precursors by rapid hydrolysis method for realizing lower temperature formation of NiFe2O4 under hydrothermal conditions. The precursor, obtained from a lower concentration of NiCl2–FeCl2 mixed solution, was almost amorphous and could be easily converted to NiFe2O4 crystal phase at around 130°C by hydrothermal treatment. On the other hand, when a higher concentration of NiCl2–FeCl2 solution or trivalent iron salt (FeCl3) was used as starting reagents, individual crystal phases such as α-Ni(OH)2, γ-Fe2O3 and α-FeOOH were recognized in precursors owing to the difference in hydrolysis rates between Ni2+ and Fe2+ (or Fe3+). These individual crystal phases involved precursors that could not be converted easily to NiFe2O4 crystal phase, but needed to treat at higher temperatures for forming NiFe2O4 at least 200°C. Thus, the co-existence of individual crystal phases in precursors might prevent the amorphous precursor from forming NiFe2O4 crystal phase. The formation of NiFe2O4 at lower temperatures is considered to be taken place preferentially from amorphous precursors than individual certain crystal phases.
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Optimum dopant of barium zirconate electrolyte for manufacturing of protonic ceramic fuel cells Reviewed
Kuroha T., Niina Y., Shudo M., Sakai G., Matsunaga N., Goto T., Yamauchi K., Mikami Y., Okuyama Y.
Journal of Power Sources 506 2021.9
Language：Japanese Publishing type：Research paper (scientific journal) Publisher：Journal of Power Sources
We examine ceramic tape-casting and anode electrolyte co-firing for large-scale manufacturing of protonic ceramic fuel cells. We confirm the reactivity of Ni, a commonly used anode, with BaZr0.8M0.2O3−δ (BZM20: M = Sc, In, Lu, Yb, Y or Gd). Addition of 0.4 mol% NiO to BZM20 and co-firing at 1778 K, produces BaM2NiO5 for M = Y and Gd. No reaction occurs for M = Sc, In, Lu and Yb. The proton conductivity of all BZM20s decreases by approximately 30% because of NiO doping and dehydration on dissolution NiO. Energy efficiency and power density calculations of the fuel cells based on measured proton and hole conductivities indicate respective decreases of approximately 10% and 75% ecause of the formation of a solid solution of NiO. We fabricate fuel cells by the tape-casting and anode electrolyte co-firing with BZM20 (M = Yb or Y). For M = Y, the cell cannot be fabricated because formation of BaY2NiO5 causes cell cracking. Conversely, when M = Yb, a cell with a maximum output of 0.5 Wcm−2 at 873 K is fabricated. Hence, BZYb20 is a suitable material for tape-casting and anode electrolyte co-firing.
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Kuroha T., Yamauchi K., Mikami Y., Tsuji Y., Niina Y., Shudo M., Sakai G., Matsunaga N., Okuyama Y.
International Journal of Hydrogen Energy 45 ( 4 ) 3123 - 3131 2020.1
Language：English Publishing type：Research paper (scientific journal) Publisher：International Journal of Hydrogen Energy
© 2019 Hydrogen Energy Publications LLC We investigated the influence of Ni on protonic ceramic fuel cells based on indium-doped barium zirconate. A tubular fuel cell was fabricated and evaluated with BaZr0.8In0.2O3−δ as an electrolyte. The maximum power density was 0.143 W cm−2 and the ohmic resistance of the electrolyte was 0.91 Ω cm2 at 873 K. We used secondary ion mass spectrometry to measure the dissolution of Ni in the electrolyte N to be 0.015. To clarify the effect of Ni on proton transport properties of BaZr0.8In0.2O3−δ, electrical conductivity and proton concentration were measured by AC impedance analysis and thermogravimetric analysis. Electrical conductivity decreased as the NiO content increased. Conversely, proton concentration was independent of the NiO content and proton diffusivity decreased. The sample density also depended on the NiO content. The density decreased as NiO content increased. These results were consistent with the density calculated based on a model describing formation of oxygen vacancies.
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Okuyama Y., Nagatomo S., Niisaka A., Matsunaga N., Sakai G., Sasamata Y., Ogura Y., Mizutani Y.
ECS Transactions 91 ( 1 ) 2653 - 2659 2019
Language：English Publishing type：Research paper (scientific journal) Publisher：ECS Transactions
© The Electrochemical Society. Steam electrolysis using a proton conducting oxide might offer low-cost hydrogen production using a combination of electrical energy and thermal energy that comes from solar energy. On the other hand, the hydrogen production efficiency is low due to the electrical leakage for the electrolysis of H2O-O2. In this study, the additive effect of methane on the hydrogen production efficiency for stem electrolysis using a proton conducting oxide was examined. The steam electrolysis was performed under a H2O-O2, H2O-CH4 atmosphere at 1073 K. The hydrogen evolution rate of the H2O-CH4 electrolysis with the Ru catalyst was in agreement with the value according to Faraday's law. The hydrogen evolution rate and the electrolysis voltage were found to increase in the order of the H2O-CH4 electrolysis with the catalyst < the H2O-CH4 electrolysis without the catalyst < the H2O-O2 electrolysis.
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Proton Conduction and Incorporation into La1−xBaxYb0.5In0.5O3−δ (共著) Reviewed
Okuyama Yuji, Ymaguchi Takuya, Matsunaga Naoki, Sakai Go
MATERIALS TRANSACTIONS 59 ( 1 ) 14 - 18 2018.1
Language：Japanese Publishing type：Research paper (scientific journal) Publisher：公益社団法人 日本金属学会
In order to clarify the effect of the dopant concentration and phase transition on the proton conduction and proton concentration, the electrical conductivity and proton concentration were determined for La<sub>1−</sub><i><sub>x</sub></i>Ba<i><sub>x</sub></i>Yb<sub>0.5</sub>In<sub>0.5</sub>O<sub>3−δ</sub> (x = 0.1. 0.3. 0.5, 0.7). The phase transition from the orthorhombic system to the cubic system was over <i>x</i> = 0.3. The proton/deuteron isotope effect on the conductivity was observed for all samples at 673 K. The proton concentration was independent of the barium content above 673 K. The proton concentration increased with the barium content below 673 K, but the concentration ratio of the proton to dopant decreased following an increase in the barium concentration. It was determined that the dopant concentration and phase transition do not have an influence on the conduction and incorporation of protons into the La<sub>1−</sub><i><sub>x</sub></i>Ba<i><sub>x</sub></i>Yb<sub>0.5</sub>In<sub>0.5</sub>O<sub>3−δ</sub>.
MISC 【 display / non-display 】
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グラファイト含有耐火れんがの熱伝導度の理論的解析(共著)
平田好洋、松永直樹、吉富丈記、加山恒夫
耐火物 65 ( 5 ) 205 - 212 2013.5
Language：Japanese Publishing type：Article, review, commentary, editorial, etc. (scientific journal) Publisher：耐火物技術協会
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高靱性、高強度の炭化ケイ素焼結体の開発（共著）
平田 好洋, 松永 直樹
材料の科学と工学 49 ( 1 ) 20 - 25 2012.2
Language：Japanese Publishing type：Research paper, summary (national, other academic conference) Publisher：日本材料科学会
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Reforming of biogas using electrochemical cell (共著)
Y. Hirata, N. Matsunaga, S. Sameshima
Journal of the Ceramic Society of Japan 119 ( 11 ) 763 - 769 2011.11
Language：English Publishing type：Article, review, commentary, editorial, etc. (scientific journal) Publisher：日本セラミックス協会
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Colloidal Processing of High Performance Silicon Carbide "jointly worked"
Journal of the Society of Power Technology, Japan 48 ( 8 ) 542 - 551 2011.8
Language：Japanese Publishing type：Research paper, summary (national, other academic conference) Publisher：The Society of Powder Technology, Japan
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多孔質セル電極内の酸化還元反応によるバイオガス改質（共著）
平田 好洋, 松永 直樹
未来材料 10 ( 11 ) 40 - 47 2010.11
Language：Japanese Publishing type：Article, review, commentary, editorial, etc. (scientific journal) Publisher：エヌ・ティー・エス
Presentations 【 display / non-display 】
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ニッケルフェライトの水熱合成と液相還元による銀触媒担時
松永直樹、石田 武、中本偉行、酒井 剛
電気化学会第92回大会 (東京農工大学 小金井キャンパス) 2025.3.18 電気化学会
Event date： 2025.3.18 - 2025.3.20
Language：Japanese Presentation type：Oral presentation (general)
Venue：東京農工大学 小金井キャンパス
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Cu置換水酸化ニッケルの熱処理による構造変化
五十嵐廉、松永直樹、酒井 剛
日本化学会九州支部フォーラム2024 2024.12.21
Event date： 2024.12.21
Language：Japanese Presentation type：Poster presentation
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高比表面積Ti-Sn複合酸化物の調製と溶媒熱処理によるアモルファス除去
永樂惠裕、松永直樹、酒井 剛
日本化学会九州支部フォーラム2024 2024.12.21
Event date： 2024.12.21
Language：Japanese Presentation type：Poster presentation
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塩基性条件下でのNi, Cu, Zn, Agの電気化学特性および湿式法によるAg-Ni複合化の検討
黒木 雅人、酒井 剛、松永 直樹
第61回化学関連支部合同九州大会 (北九州国際会議場) 2024.6.29 高分子学会九州支部, 繊維学会西部支部, 日本農芸化学会西日本支部, 化学工学会九州支部, 日本化学会九州支部, 有機合成化学協会九州山口支部, 電気化学会九州支部, 日本分析化学会九州支部, 北九州市
Event date： 2024.6.29
Language：Japanese Presentation type：Poster presentation
Venue：北九州国際会議場
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Ti3+置換β型水酸化ニッケルの構造解析と熱処理による構造変化
恒成 尚俊、松永 直樹、酒井 剛
第61回化学関連支部合同九州大会 (北九州国際会議場) 2024.6.29 高分子学会九州支部, 繊維学会西部支部, 日本農芸化学会西日本支部, 化学工学会九州支部, 日本化学会九州支部, 有機合成化学協会九州山口支部, 電気化学会九州支部, 日本分析化学会九州支部, 北九州市
Event date： 2024.6.29
Language：Japanese Presentation type：Poster presentation
Venue：北九州国際会議場
Industrial property rights 【 display / non-display 】
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α型水酸化ニッケルおよびその製造方法
酒井 剛, 松永 直樹
Applicant：国立大学法人宮崎大学
Application no：特願2013-181414 Date applied：2013.9.2
Announcement no：特開2015-048279 Date announced：2015.3.16
Patent/Registration no：特許6172634 Date registered：2017.7.14
Country of applicant：Domestic
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正極材料及び固体酸化物形燃料電池
平田 好洋, 鮫島 宗一郎, 松永 直樹, 下之薗 太郎
Applicant：国立大学法人 鹿児島大学
Application no：特願2007-189973 Date applied：2007.7.20
Announcement no：特開2009-026659 Date announced：2009.2.5
Patent/Registration no：特許第5212967号 Date registered：2013.3.8
Country of applicant：Domestic
Awards 【 display / non-display 】
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若林論文賞
2013.4 耐火物技術協会
Y. Hirata, N. Matsunaga, J. Yoshitomi, T. Kayama
Award type：Honored in official journal of a scientific society, scientific journal Country：Japan
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Best Poster Award
2013.1 The 14th International Symposium on Eco-materials Processing and Design (ISEPD2013)
Naoki Furukawa, Yoshihiro Hirata, Soichiro Sameshima, Naoki Matsunaga
Award type：Award from international society, conference, symposium, etc. Country：Japan
Grant-in-Aid for Scientific Research 【 display / non-display 】
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銀を用いた次世代アルカリ形燃料電池用電極触媒の調製と酸素還元活性評価
Grant number：24K08032 2024.04 - 2027.03
日本学術振興会 科学研究費助成事業 基金 基盤研究(C)
松永直樹
Authorship：Principal investigator
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貴金属フリーな次世代燃料電池用電極触媒の合成と高性能化のための合成指針の確立
Grant number：16K05941 2016.10 - 2019.03
日本学術振興会 科学研究費補助金 基盤研究(C)
Authorship：Principal investigator
アニオン交換膜形燃料電池は、電極触媒の白金量低減を可能にする次世代燃料電池として期待される。ただし既存の塩基性条件下で用いる電極触媒の酸素還元活性は、白金の酸素還元活性より劣る。最近、本研究グループでは遷移金属化合物を積層した白金板の酸素還元活性が白金と同等以上の触媒活性を示すことを見出した。本研究では電極触媒の白金量低減を目的として、耐塩基性の高い遷移金属/遷移金属化合物複合体を調製し、塩基性条件下での酸素還元活性の有無を検証するとともに、複合体の酸素還元活性を向上させる最適条件を明らかにする。本研究成果は、塩基性条件下で高い酸素還元活性を示す電極触媒の設計指針の構築への寄与が期待される。
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Electrochemical synthesis and photocatalytic properties of Al2O3-ITO-TiO2 system film
Grant number：21760535 2009.04 - 2012.03
Japan Society for the Promotion of Science Grant-in-Aid for Scientific Research Grant-in-Aid for Young Scientists(B)
Naoki Matsunaga
Authorship：Principal investigator
Available Technology 【 display / non-display 】
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アルカリ用電極触媒を目指した金属複合水酸化物に関する合成
人工骨を目指したセラミックスに関する合成Message：・共同研究の希望テーマ：無機材料・電気化学に関する研究
・セラミックス材料の合成（特に湿式法）、利用、分析に関すること、また強度に関することであればご相談ください。
Committee Memberships 【 display / non-display 】
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Sensors and Actuators B: Chemical reviewer
2025.2
Committee type：学協会
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アジア化学センサ国際会議 アジア化学センサ国際会議実行委員会 委員
2024.8 - 2024.12
Committee type：学協会
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日本セラミックス協会 2024年年会優秀ポスター発表賞選考委員
2024.3
Committee type：学協会
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電気化学会九州支部 トークシャワー・イン・九州2023世話人
2023.9
Committee type：学協会
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日本セラミックス協会 日本セラミックス協会九州支部 2021年度秋季研究発表会世話人
2021.3 - 2021.11
Committee type：学協会
Social Activities 【 display / non-display 】
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宮崎県立宮崎大宮高等学校 文化情報科探求課題発表会におけるアドバイザー教員
Role(s)： Advisor
2025.3.14
Audience： High school students
Type：Research consultation
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アドベンチャー工学部
Role(s)： Organizing member, Demonstrator
宮崎大学工学部 令和5年アドベンチャー工学部 2023.11.19
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令和２年度地域との協働による高等学校教育改革推進事業におけるアドバイザー教員
Role(s)： Advisor
2020.7.10 - 2021.3.15
Audience： High school students
Type：Research consultation
Academic Activities 【 display / non-display 】
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令和６年度宮崎県高文連自然科学プレゼンテーション大会
Role(s)： Review, evaluation
宮崎県高文連自然科学部門 2024.11.3
Type：Scientific advice/Review