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Faculty of Education Science education |
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Professor |
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ARII Hidekazu
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Research Areas 【 display / non-display 】
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Nanotechnology/Materials / Inorganic/coordination chemistry
Education 【 display / non-display 】
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Nagoya Institute of Technology Graduate School of Engineering Department of Material Science and Engineering
1998.4 - 2003.3
Country：Japan
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Nagoya Institute of Technology Faculty of Engineering Department of Chemistry
1994.4 - 1998.3
Country：Japan
Papers 【 display / non-display 】
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Preparations of trans- and cis-μ-1,2-Peroxodiiron(III) Complexes Reviewed
Y. Kajita, M. Kubo, H. Arii, S. Ishikawa, Y. Saito, Y. Wasada-Tsutsui, Y. Funahashi, T. Ozawa, H. Masuda
Molecules 29 ( 1 ) 2024.1
Language：English Publishing type：Research paper (scientific journal) Publisher：Molecules
The iron(II) complex with cis,cis-1,3,5-tris(benzylamino)cyclohexane (Bn3CY) (1) has been synthesized and characterized, which reacted with dioxygen to form the peroxo complex 2 in acetone at −60 °C. On the basis of spectroscopic measurements for 2, it was confirmed that the peroxo complex 2 has a trans-μ-1,2 fashion. Additionally, the peroxo complex 2 was reacted with benzoate anion as a bridging agent to give a peroxo complex 3. The results of resonance Raman and 1H-NMR studies supported that the peroxo complex 3 is a cis-μ-1,2-peroxodiiron(III) complex. These spectral features were interpreted by using DFT calculations.
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Dehydrogenative Annulation of Silylated 1H-Indoles with Alkynes via Silyl Migration Reviewed
Arii H., Nakane D., Nakao K., Masuda H., Kawashima T.
Organic Letters 25 ( 29 ) 5416 - 5420 2023.7
Authorship：Lead author Language：English Publishing type：Research paper (scientific journal) Publisher：Organic Letters
We investigated the dehydrogenative annulation of silylated 1H-indole derivatives with alkynes to synthesize a silole-fused indole. The addition of the in situ generated silylium ion to alkynes was followed by the sila-Friedel-Crafts reaction via silyl migration, realizing regioselective dehydrogenative annulation controlled by the steric bulkiness of a base. The optical properties of the obtained siloloindoles indicated fluorescence of which the intensity depends on the location of the fused silole.
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Tomoko Tanaka, Chie Kuroki, Hidekazu Arii
Memoirs of the Faculty of Education, Miyazaki University. 98 102 - 111 2022.3
Authorship：Corresponding author Language：Japanese Publishing type：Research paper (scientific journal)
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Preparation of Flavylium Ion Adsorbed on Zeolite as a Repeatable pH Indicator Reviewed
Arii Hidekazu, Kuroki Chie
The Joint Journal of the National Universities in Kyushu. Education and Humanities 8 ( 2 ) No.5 2022.3
Language：Japanese Publishing type：Research paper (scientific journal)
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Arii H., Nakao K., Masuda H., Kawashima T.
ACS Omega 7 ( 6 ) 5166 - 5175 2022.2
Authorship：Lead author Language：Japanese Publishing type：Research paper (scientific journal) Publisher：ACS Omega
A strong Lewis acid silylium ion was utilized for dehydrogenative annulation between dialkyl(1-naphthyl)silanes 1 and aldehydes 2. Silane 1a was reacted with [Ph3C][B(C6F5)4] in the presence of 2,6-di-tert-butyl-4-methylpyridine and aldehydes 2 to afford the annulation product, 1-silabenzo[d,e]isochromanes 3, in moderate isolated yields. The annulation occurred only at the 8-position on the 1-naphthyl group. The silylium ion-promoted hydrosilylation proceeded competitively to afford silyl ethers 4 via the same intermediates, silylcarboxonium ions, in the dehydrogenative annulation. The ratio of 3 and 4 was affected by solvents and the electronic properties of aromatic aldehydes; for example, the use of less polar solvents and that of benzaldehydes with an electron-withdrawing group at the para-position predominantly yielded 3. This annulation reaction was applicable to aldehydes bearing a heteroaromatic group and aliphatic alkyl groups. Judging from these results, both the formation of silylcarboxonium ions by in situ-generated silylium ions and the electrophilic aromatic substitution are important for this annulation reaction.
MISC 【 display / non-display 】
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ジヒドロジシランから誘導される多核¬白金–ケイ素錯体の合成 Invited
有井 秀和, 持田 邦夫
ケイ素化学協会誌 25 28 - 31 2010.11
Language：Japanese Publishing type：Article, review, commentary, editorial, etc. (scientific journal)
Grant-in-Aid for Scientific Research 【 display / non-display 】
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イオンの大きさや電荷を可視化する実験手法ならびに教材の開発
Grant number：23K02792 2023.04 - 2026.03
独立行政法人日本学術振興会 科学研究費補助金 基盤研究(C)
有井秀和
Authorship：Principal investigator Grant type：Competitive
中学校の学習指導内容の「水溶液とイオン」において、イオンは原子が電子を放出する、あるいは原子が電子を受け取ることにより生じる化学種であり、電気泳動によりイオンが帯電していることを確認している。電気泳動ではイオンが電場の中で力を受けて移動しており、イオンの大きさあるいは価数に依存して移動距離が変化することが知られている。本研究では、従来まで定性的な実験として行われていた電気泳動に定量性を加えることを目的とし、一般的な金属イオンや錯塩を利用した電気泳動実験の確立を目指す。また発色団を持つ配位子の導入により、無色イオンの可視化も試みる。