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Affiliation |
Engineering educational research section Electrical and Electronic System Program |
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Associate Professor |
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Laboratory Address |
工学部E棟204号室 |
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Laboratory Phone number |
0985-58-7353 |
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Contact information |
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Homepage |
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External Link |
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Related SDGs |
HIGASHI Tomohiro
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Degree 【 display / non-display 】
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博士(工学) ( 2015.3 長崎大学 )
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修士(工学) ( 2012.3 長崎大学 )
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学士(工学) ( 2010.3 長崎大学 )
Research Areas 【 display / non-display 】
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Manufacturing Technology (Mechanical Engineering, Electrical and Electronic Engineering, Chemical Engineering) / Catalyst and resource chemical process
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Nanotechnology/Materials / Functional solid state chemistry
Education 【 display / non-display 】
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Nagasaki University
2012.4 - 2015.3
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Nagasaki University
2010.4 - 2012.3
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Nagasaki University
2006.4 - 2010.3
Campus Career 【 display / non-display 】
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University of Miyazaki Engineering educational research section Electrical and Electronic System Program Associate Professor
2025.04 - Now
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University of Miyazaki Organization for Promotion of Research and Industry-Academic Regional Collaboration Institute for Tenure Track Promotion Assistant Professor
2023.07 - 2025.03
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University of Miyazaki Organization for Promotion of Career Management Institute for Tenure Track Promotion Assistant Professor
2021.11 - 2023.06
External Career 【 display / non-display 】
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The University of Tokyo Department of Chemical System Engineering Assistant Professor
2017.4 - 2021.10
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The University of Tokyo Department of Chemical System Engineering Researcher
2015.4 - 2017.3
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日本学術振興会 日本学術振興会特別研究員
2013.4 - 2015.3
Country:Japan
Professional Memberships 【 display / non-display 】
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日本ポーラログラフ学会
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触媒学会
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電気化学会
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日本化学会
Papers 【 display / non-display 】
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Yoshiyama K., Xiao T., Aso Y., Hie M., Yoshino K., Higashi T.
ACS Applied Energy Materials 9 ( 7 ) 4497 - 4510 2026.4
Authorship:Last author, Corresponding author Language:English Publishing type:Research paper (scientific journal)
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Optimized hydrogen evolution on ultrathin CrOx-modified Ir nanoparticles: mechanism and control of proton hopping and particle aggregation Reviewed International coauthorship
Xiao T., Sun C., Yan M., Nakabayashi M., Shibata N., Domen K., Higashi T.
Journal of Materials Chemistry A 2026
Authorship:Last author, Corresponding author Language:English Publishing type:Research paper (scientific journal)
DOI: 10.1039/d6ta02513g
DOI: 10.1039/d6ta02513g
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Electrochemical Identification of Surface States Limiting Overall Water Splitting in Particulate Oxynitride Photocatalysts Invited Reviewed International coauthorship
Tomohiro Higashi, Tian Xiao, Faze Wang, Jiadong Xiao, Yuriy Pihosh, Atsushi Ohnishi, Takashi Hisatomi, Kazunari Domen
ACS Energy Letters 11 ( 1 ) 673 - 680 2025.12
Authorship:Lead author, Corresponding author Language:English Publishing type:Research paper (scientific journal)
DOI: 10.1021/acsenergylett.5c03342
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Xiao Tian, Yoshiyama Koichi, Yoshino Kenji, Higashi Tomohiro
Discover Electrochemistry 2 ( 1 ) 11 2025.4
Authorship:Last author, Corresponding author Language:English Publishing type:Research paper (scientific journal)
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Estimating the quasi-Fermi level of holes at the surface of semiconductor photoanodes using outer-sphere redox couples Reviewed International coauthorship
Shioiri Yuu, Obata Keisuke, Kawase Yudai, Higashi Tomohiro, Katayama Masao, Schleuning Markus, van de Krol Roel, Friedrich Dennis, Abdi Fatwa Firdaus, Takanabe Kazuhiro
Nature Communications 16 ( 1 ) 3688 2025.4
Language:English Publishing type:Research paper (scientific journal)
DOI: 10.1038/s41467-025-58837-9
Books 【 display / non-display 】
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光触媒および光電極を用いた水分解反応によるソーラー水素製造
東 智弘, 堂免 一成( Role: Joint author)
株式会社オプトロニクス社 2018
Book type:Textbook, survey, introduction
MISC 【 display / non-display 】
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The 71st Annual Meeting of the Polarographic Society of Japan (PSJ)
Higashi Tomohiro
Review of Polarography 72 ( 1 ) 31 - 34 2026.5
Authorship:Lead author Language:Japanese Publishing type:Meeting report Publisher:The Polarographic Society of Japan
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東 智弘
ACS Energy Letters 11 ( 1 ) 673 - 680 2025.12
Language:English Publishing type:Rapid communication, short report, research note, etc. (scientific journal) Publisher:ACS Publications
Oxynitride photocatalysts drive the hydrogen and oxygen evolution reactions under visible light with sacrificial reagents, but overall water splitting remains challenging, pointing to unresolved interfacial energetics. Here we integrate SrTaO2N and the (BaxSr1–x)TaO2N solid solution into particulate photoelectrodes and quantitatively probe their semiconductor properties at the solid/liquid interface. Beyond the rectifying behavior established for single-crystal photoelectrodes, electrochemical measurements using a reversible Fe3+/Fe2+ redox couple identify a defect-derived surface state located at 0.5 V vs the reversible hydrogen electrode in photocatalysts that mediates irreversible electron transfer. While this state enables half-reactions and rationalizes Z-scheme water splitting with suitable mediators, it promotes carrier recombination and thereby suppresses overall water splitting. This study establishes an electrochemical methodology that bridges photocatalyst powders and interfacial energetics and indicates that eliminating or passivating the defect states should enable overall pure water splitting in oxynitrides.
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東 智弘
Nature Communications 16 ( 1 ) 3688 2025.4
Language:English Publishing type:Rapid communication, short report, research note, etc. (scientific journal) Publisher:Springer Science and Business Media LLC
Semiconductor electrodes can catalyze photo-induced redox reactions with light illumination. Photoexcitation produces excited carriers that subsequently transfer to the front and back contacts as determined by the bulk and surface properties of the photoelectrodes. This transfer defines the resultant quasi-Fermi levels of the photo-generated carriers at the photoelectrode surface, which, in turn, impacts the efficiency of surface photoelectrochemical reactions. However, determining such quasi-Fermi levels is not a simple task. In this study, we introduce a method for estimating the quasi-Fermi level of holes using outer-sphere electron transfer reactions. The quasi-Fermi level of holes is estimated by linking the oxidation photocurrent on photoanodes to the separately measured electrode potential on a stable metal electrode. Using this method, the quasi-Fermi level of holes at the surface is monitored in response to variations in applied potential and light intensity. This approach effectively separates the photocurrents of the CdS model electrode between surface redox reaction and photocorrosion, while concurrently quantifying the dynamic quasi-Fermi level at the surface. This work facilitates quantitative understanding of photoelectrochemical reactions on semiconductor electrodes to design green chemical transformation systems.
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東 智弘, 吉野 賢二
ChemNanoMat 11 ( 1 ) e202400536 2025.1
Language:English Publishing type:Rapid communication, short report, research note, etc. (scientific journal) Publisher:Wiley
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Photoelectrochemical properties of p-type CuBi2O4 prepared by spray pyrolysis
Wakishima Kaisei, Higashi Tomohiro, Nagaoka Akira, Yoshino Kenji
53 75 - 78 2024.10
Language:Japanese Publishing type:Rapid communication, short report, research note, etc. (bulletin of university, research institution) Publisher:Faculty of Engineering, University of Miyazaki
DOI: 10.34481/0002000819
Presentations 【 display / non-display 】
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半導体光電極/水溶液界面の設計による水分解特性の向上 Invited
東 智弘
第73回応用物理学会春季学術講演会 2026.3.15
Event date: 2026.3.15 - 2026.3.18
Language:Japanese Presentation type:Oral presentation (invited, special)
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Enhanced Oxygen Evolution Performance of Semitransparent NiFeCoOx Thin-Film Cocatalysts for Photoelectrochemical Water Splitting International conference
Koichi Yoshiyama, Tian Xiao, Kenji Yoshio, Tomohiro Higashi
Materials Research Meeting (MRM) 2025 2025.12.10
Event date: 2025.12.9 - 2025.12.12
Language:English Presentation type:Oral presentation (general)
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LaFeO3光電極のアニール温度の変化に伴う光電気化学特性の評価
永峰 琢也, 麻生 裕介, 東 智弘
第71回ポーラログラフィーおよび電気分析化学討論会 2025.10.22
Event date: 2025.10.22 - 2025.10.23
Presentation type:Poster presentation
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Interfacial Design of Semitransparent Photoelectrodes for Visible-Light-Driven Green Hydrogen Production Invited International conference
Tomohiro Higashi
2025 International G-LAMP Symposium on Renewable Energy Technologies 2025.8.28
Event date: 2025.8.28 - 2025.8.29
Language:English Presentation type:Oral presentation (invited, special)
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Interfacial Engineering of Visible-Light-Absorbing Semitransparent Photoelectrodes for Durable Solar Water Splitting Invited International conference
Tomohiro Higashi
247th ECS Meeting 2025.5.18
Event date: 2025.5.16 - 2025.5.21
Language:English Presentation type:Oral presentation (invited, special)
Awards 【 display / non-display 】
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Best Presenter Award in APL Materials
2023.9 Materials Oceania 2023
Award type:Award from international society, conference, symposium, etc.
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President Award in Academic Excellence
2015.3 Nagasaki University
Tomohiro Higashi
Grant-in-Aid for Scientific Research 【 display / non-display 】
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タンデム型水分解セルの長寿命化に向けた半透明な光電極への表面修飾法の開発
Grant number:23K04917 2023.04 - 2027.03
独立行政法人日本学術振興会 科学研究費基金 基盤研究(C)
Authorship:Principal investigator
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光電極/水溶液界面で起こる水分解反応の精密電気化学測定
Grant number:19K15670 2019.04 - 2022.03
科学研究費補助金 若手研究
Authorship:Principal investigator
Committee Memberships 【 display / non-display 】
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The Polarographic Society of Japan Director of general affairs
2026.1
Committee type:学協会
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The Polarographic Society of Japan Director of annual meeting
2025.1 - 2026.12
Committee type:学協会
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The Polarographic Society of Japan Councilor
2023.1
Committee type:学協会